Basic Principles, Canonical and Grand Canonical ensembles : Concept of statistical distribution, phase space, density of states ,Liouville's theorem, systems and ensemble, entropy in statistical mechanics, Connection between thermodynamic and statistical quantities, micro canonical ensemble, equation of state, specific heat and entropy of a perfect gas using microcanonical ensemble.
Canonical ensemble, thermodynamic functions for the canonical ensemble, calculation of mean value, energy fluctuation in a gas, grand canonical ensemble, thermodynamic functions for the grand canonical ensemble, density fluctuations.